I don't know of any GM part number SPECIFICALLY stating "Residual Pressure Valve", so it may not have been able to have been ordered separately. You can see from the exploded diagram below that the RPV isn't even shown! However, there's a "Repair Unit" (Group 4.649) for the Camaro as P/N 5462708 (1967 with disc brakes) or P/N 5468449 (1968 with disc brakes), but it doesn't say what's included in the kit!
There are two "Valve assemblies" listed in the P&A. The first is under Group 4.657 and it's P/N 5462642, ("VALVE ASSY, MAIN CYLINDER CHECK"), and it's used on ALL 67-69 cars ("as required"). The second is under Group 4.658 and it's P/N 5462684, ("VALVE ASSY, POWER BRAKE CYLINDER"), and it's used on the 67-68 Camaro and the 68-69 Nova. But again, no REAL description what either these valves are for! If I were to guess, I'd say the RPV is probably P/N 5462642, but that's just a WAG.
Napa might be able to get the RPV, but to be honest, I've never researched this very much.
Ed